The first excited single-proton resonance in 15F by complex-scaled Green's function method

The complex-scaled Green's function(CGF)method is employed to explore the single-proton resonance in 15F.Special attention is paid to the first excited resonant state 5/2+,which has been widely studied in both theory and experiments.However,past studies generally overestimated the width of the 5/2+state.The predicted energy and width of the first excited resonant state 5/2+by the CGF method are both in good agreement with the experimental value and close to Fortune's new estimation.Furthermore,the influence of the potential parameters and quadruple deformation effects on the resonant states are investigated in detail,which is helpful to the study of the shell structure evolution.     

Effect of polyethylene glycol on corrosion of fresh macroporous silicon in 1.0 M NaOH and application in determination of porosity and thickness by gravimetric measurement

Abstract

This work presents on improvement in gravimetric measurement for determining the porosity and thickness of microporous silicon. Herein, the corrosion of fresh macroporous silicon (f-MPSi) in 1.0?M NaOH with different concentrations of polyethylene glycol (PEG 200/400/600) was studied by weight loss measurement and scanning electron microscopy (SEM). The results showed that the corrosion rate decreased with increasing polyethylene glycol concentration, and increased with an increase in temperature. Polyethylene glycol can inhibit the corrosion of f-MPSi in NaOH solution. Moreover, 1.0?M NaOH/PEG 600 (10%) can be used as the optimized solution to remove f-MPSi for measuring its porosity and thickness by gravimetric measurement.     

Solitons and rogue waves of the quartic nonlinear Schrödinger equation by Riemann–Hilbert approach

Nonlinear Dynamics - We systematically develop a Riemann–Hilbert approach for the quartic nonlinear Schrödinger equation on the line with both zero boundary condition and nonzero...     

Facile fabrication of oxygen-doped carbon nitride with enhanced visible-light photocatalytic degradation of methyl mercaptan

Research on Chemical Intermediates - Element doping has demonstrated an effective strategy for enhancing photocatalytic performance of carbon nitride (CN). Herein, we reported that oxygen-doped CN...     

d-Orbital Reconstructions Forced by Double Bow-Shaped Deformations and Second Coordination Sphere Effects of Cu(II) Heme Analogs in HER**

Both geometric architecture and electronic configurations of heme proteins contribute to its activity. In this work we designed and synthesized a series of four copper(II) porphyrin complexes ( 4 -, 3 -, 2 - and 1 -Cu) where the molecular conformations are modulated by a pair of stepwise shortened straps on the same porphyrin side (cis-ortho) to give double bow-shaped skeletons. Single crystal structures demonstrate that the straps gradually increase the saddle deformation and the deviation of the metal centers, which is in accordance with two, unusual d-orbital reconstructions of two different ground states, as revealed by 4 K EPR and DFT calculations. In the study of the electrocatalytic hydrogen evolution reaction (HER), 1 -Cu, with the shortest straps, showed the most apparent improvement of activity. Second coordination sphere (SCS) effects created by the double bow-shaped architecture and the strong saddle porphyrin core in 1 -Cu are found to play key roles in proton trapping during the catalytic process. The work contributes a novel strategy to improve the catalytic performance of heme analogs through ligand geometric modulation.     

Heterointerface Engineering of ZnO/CdS Heterostructures through ZnS Layers for Photocatalytic Water Splitting

Solar-driven water splitting to produce clean and renewable hydrogen offers a green strategy to address the energy crisis and environmental pollution. Heterostructure catalysts are receiving increasing attention for photocatalytic hydrogen generation. ZnO/ZnS/CdS and ZnO/CdS heterostructures have been successfully designed and prepared according to two different strategies. By introducing a heterointerface layer of ZnS between ZnO and CdS, a Z scheme charge-transfer channel was promoted and achieved superior photocatalytic performance. A highest hydrogen generation rate of 156.7 μmol g⁻¹ h⁻¹ was achieved by precise control of the thickness of the heterointerface layer and of the CdS shell. These findings demonstrated that heterostructures are promising catalysts for solar-driven water splitting, and that heterointerface engineering is an effective way to improve the photocatalytic properties of heterostructures.     

A novel multi-claw reactive flame retardant derived from DOPO for endowing lyocell fabric with high effective flame retardancy

Cellulose - A novel DOPO derived multi-claw reactive flame retardant (DMCFR) was designed to improve the flame retardancy of lyocell fabric. The chemical structure of DMCFR was identified by proton...     

Chamigrane Sesquiterpenes from Cultures of Fungus Antrodiella albocinnamomea

Chemistry of Natural Compounds - A new chamigrane sesquiterpene, antroalbol F (1), along with one known compound, acaciicolinol C (2), were isolated from cultures of the fungus Antrodiella...     

Fully Chemical Recyclable Poly(γ-butyrolactone)-based Copolymers with Tunable Structures and Properties

Chinese Journal of Polymer Science - The emerging chemical recyclable polymers, such as poly(γ-butyrolactone) (PGBL) and poly((R)-3,4-trans six-membered ring-fused GBL) (P((R)-M)), provide a...     

Subtle Alignment of Organic Semiconductors at the Donor/Acceptor Heterojunction Facilitates the Photoelectric Conversion Process

Chinese Journal of Polymer Science - The aligned molecular packing structure is vital to the anisotropic charge transport in conjugated polymer and small molecule thin films. However, how this...